Brago & Sherry:Beat them in the Story mode
Kanchome & Folgore:Beat them in the Story mode
Kolulu & Lori:Beat them in the Story mode
Rops & Apolo:Beat them in the Story mode Tia & Megumi:Beat them in the Story mode
Berserk Brago and Sherry
lay through Challenge mode or Survival mode once and beat them when you battle them.
Poygon & Raiku Sensei
lay challenge mode, 60 sec., Normal mode, with Zeno & Dufort and win every battle by letting the time run out.
Rauzaruk Zatch & Kiyo:Get 100% Zatch Collection then put Up,L,R,Down,L,R,L,Left,Right,R at title screen then play story mode again
Zeno & Dufort
lay Challenge mode with Zatch & Kiyo in Normal and 60 sec, always beating every round with above 50% of life